1.Bring cream and butter to the boil in a small saucepan over medium heat. Pour over chopped chocolate in a small heatproof bowl, stirring until chocolate melts. Stir in rind and liqueur. Cover; refrigerate, stirring occasionally, for 30 minutes or until mixture starts to thicken but does not set.
2.Roll rounded teaspoons of mixture into balls. In a single layer, place on a baking-paper-lined tray. Refrigerate truffles until firm.
3.Melt extra chocolate in a medium heatproof bowl over a medium saucepan of simmering water until smooth (don’t let water touch base of bowl).
4.Dip truffles in chocolate, then quickly and gently roll between palms of hands to coat evenly. Return to tray. Refrigerate for 4 hours or until firm.
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